文献类型：期刊文献

英文题名：A three-dimensional cadmium(II) coordination polymer: poly[[[μ-4,4′-(propane-1,3-diyl)dipyridine-κ²N:N]-(μ-3,3′-thiodipropionato-κ³O,O′:O)-cadmium(II)] monohydrate]

作者：Hao, Xiao-Min[1,2];Chen, Gang[1];Gu, Chang-Sheng[2];Liu, Ji-Wei[3]

机构：[1]Harbin Inst Technol, Dept Chem, Harbin 150001, Peoples R China;[2]Guangdong Ocean Univ, Dept Appl Chem, Zhanjiang 524088, Peoples R China;[3]Daqing Petr Inst, Coll Chem & Chem Technol, Daqing 163318, Peoples R China

年份：2014

卷号：70

起止页码：712

外文期刊名：ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:000339013000017)、、WOS

基金：The authors thank the National Natural Science Foundation of China (grant No. 21271055), the Foundation of Guangdong Province (grant No. 2011B090400415), Guangdong Ocean University, Harbin Institute of Technology and Daqing Petroleum Institute for supporting this work.

语种：英文

外文关键词：crystal structure; Cd-II complex; 4,4 '-(propane-1,3-diyl)dipyridine; 3,3 '-thiodipropionate; three-dimensional coordination polymer

外文摘要：In the title coordination polymer, {[Cd(C6H8O4S)(C13H14N2)]center dot H2O}(n), the Cd-II atom displays a distorted octahedral coordination, formed by three carboxylate O atoms and one S atom from three different 3,3'-thiodipropionate ligands, and two N atoms from two different 4,4'-(propane-1,3-diyl)dipyridine ligands. The Cd-II centres are bridged through carboxylate O atoms of 3,3'-thiodipropionate ligands and through N atoms of 4,4'-(propane-1,3-diyl) dipyridine ligands to form two different one-dimensional chains, which intersect to form a two-dimensional layer. These two-dimensional layers are linked by S atoms of 3,3'-thiodipropionate ligands from adjacent layers to form a three-dimensional network.