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A New Two-Dimensional Silver Coordination Polymer Constructed by 1,3-Bis(4-pyridyl)propane and 2,6-Dichlorophenylacetic Acid: Synthesis, Structure, Luminescence and Thermal Stable Properties  ( SCI-EXPANDED收录)   被引量:6

文献类型:期刊文献

英文题名:A New Two-Dimensional Silver Coordination Polymer Constructed by 1,3-Bis(4-pyridyl)propane and 2,6-Dichlorophenylacetic Acid: Synthesis, Structure, Luminescence and Thermal Stable Properties

作者:Hao, Xiao-Min[1,2];Chen, Gang[1];Gu, Chang-Sheng[2]

机构:[1]Harbin Inst Technol, Dept Chem, Harbin 150006, Peoples R China;[2]Guangdong Ocean Univ, Dept Appl Chem, Zhanjiang, Peoples R China

年份:2014

卷号:26

期号:17

起止页码:5805

外文期刊名:ASIAN JOURNAL OF CHEMISTRY

收录:SCI-EXPANDED(收录号:WOS:000343769500108)、、WOS

基金:This research was financially supported by the Foundation of Guangdong Province (No. 2011B090400415), Foundation of zhanjian city (No. 2011C3108001) and National Natural Science Foundation of China (No. 21271055).

语种:英文

外文关键词:Ag(I) coordinated polymer; Crystal structure; Luminesce

外文摘要:A novel complex 1 of {[Ag(bpp)(dcpa)]H2O}(n) [Hdcpa: 2,6-dichlorophenylacetic acid; bpp: 1,3-bis(4-pyridyl)propane] was synthesized and characterized by elemental analysis, IR, TGA, X-ray single crystal diffraction. The carboxylate oxygens of the Hdcpa ligands connect one Ag(I) ion in bidentate chelating mode to form mononuclear silver building blocks, which are into a 1D infinite chain through trans-bpp ligands. A two-dimensional network consist of adjacent Ag-bpp chain through Ag-Ag interaction. Furthermore, the luminescent property of complex 1 was investigated at room temperature. CCDC: 996495.

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