文献类型：期刊文献

英文题名：Bis(1H-imidazole-κN³)bis(4-methylbenzoato-κO)-zinc(II) 4-methylbenzoic acid disolvate

作者：Gu, Chang-Sheng; Hao, Xiao-Min; Song, Wen-Dong; Yan, Jian-Bin

机构：[1]Guangdong Univ Ocean, Dept Appl Chem, Zhanjiang 524006, Peoples R China

年份：2007

卷号：63

起止页码：m895

外文期刊名：ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

收录：SCI-EXPANDED(收录号：WOS:000245434500110)、、WOS

语种：英文

外文摘要：The molecular structure of the title compound, [ Zn( C8H7O2)(2)( C7H6N2)(2)]center dot 2C(8)H(8)O(2), is composed of a mononuclear Zn II complex, which possesses twofold rotation symmetry, and two uncoordinated 4-methylbenzoic acid molecules. The Zn II atom displays a four-coordinate distorted tetrahedral configuration, formed by two carboxylate O atoms of two monodentate 4-methylbenzoate ligands and two N atoms of two benzimidazole molecules. In the crystal structure, complex molecules are linked by the 4-methylbenzoic acid molecules via N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds, giving rise to the formation of a supramolecular structure.