文献类型：期刊文献

英文题名：Microwave-Assisted Biomass Pyrolysis to Hydrocarbons: A Review of Catalyst Evolution from Single-Function to Multi-Site Composites

作者：Xian, Shengxian[1,2];Liu, Jiurun[1];Xu, Qing[1,2]

机构：[1]Guangdong Ocean Univ, Coll Ocean Engn & Energy, 1 Haida Rd, Zhanjiang 524088, Peoples R China;[2]Guangdong Prov Key Lab Intelligent Equipment South, Zhanjiang 524088, Peoples R China

年份：2026

卷号：16

期号：5

外文期刊名：CATALYSTS

收录：SCI-EXPANDED(收录号：WOS:001774320400001)、、EI(收录号：20262220790562)、Scopus(收录号：2-s2.0-105039991021)、WOS

基金：This work was supported by the National Natural Science Foundation of China (No.52476190), the National Natural Science Foundation of China (No. 52376171), Joint Training Demonstration Base Project for Graduate Students of "Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences" in Guangdong Province, Zhanjiang Science and Technology Plan Project (2025A401002), Guangdong Basic and Applied Basic Research Foundation (2023A1515110541), Guangdong Basic and Applied Basic Research Foundation (2025A1515010722), Characteristic and Innovative Projects of General Institutions of Higher Education in Guangdong Province (2025KTSCX044), Youth S&T Talent Support Programme of Guangdong Provincial Association for Science and Technology (SKXRC2025404), Zhanjiang Non-Funded Science and Technology Research Program Projects (2025B01054).

语种：英文

外文关键词：microwave-assisted pyrolysis; composite catalyst; co-pyrolysis; monocyclic aromatics; hierarchical zeolite; catalyst deactivation

外文摘要：Microwave-assisted pyrolysis (MAP) has emerged as a revolutionary technology for converting solid waste into high-value hydrocarbons. However, conventional pyrolysis and traditional single-function catalysts often face an inevitable "performance trade-off" involving severe mass transfer resistance, poor microwave absorption, and rapid coking. This review systematically summarizes the recent evolution of catalyst design toward advanced multi-site composites. It highlights the synergistic mechanisms of integrating microwave-responsive cores, hierarchical pore networks, and metal-acid bifunctional sites to achieve ultrafast localized heat transfer, targeted bond cleavage, and in-situ coking suppression. Furthermore, this paper critically examines current bottlenecks in scaling MAP to industrial levels. To address these challenges, we discuss emerging solutions, including hydrogen-enriched co-pyrolysis, non-destructive in-situ regeneration, and the integration of machine learning frameworks for intelligent process optimization.