文献类型：期刊文献

英文题名：Syntheses, Structures and Luminescent Properties of the Cadmium(II) Complex with 3,3′-Thiodipropionic Acid

作者：Gu Chang-Sheng[1];Hao Xiao-Min[1];Zhang Zhu-Yan[2];Ji Li-Li[3];Li Yong[1];Song Wen-Dong[3]

机构：[1]Guangdong Ocean Univ, Dept Appl Chem, Zhanjiang 524088, Guangdong, Peoples R China;[2]Harbin Med Univ, Coll Pharm, Harbin 150081, Peoples R China;[3]Zhejiang Ocean Univ, Innovat & Applicat Inst, Zhoushan, Zhejiang 316022, Peoples R China

年份：2017

卷号：36

期号：3

起止页码：478

外文期刊名：CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:000402167200015)、、Scopus(收录号：2-s2.0-85017008638)、WOS

基金：This work was supported by the National Natural Science Foundation of China (No. 51302067) and the Team of Guangdong Ocean University (No. 1312435)

语种：英文

外文关键词：cadmium complex; 3,3 '-thiodipropionic acid; crystal structure

外文摘要：One new luminescent material of complex {[Cd(DPA)(H2O)(2)]center dot(H2O)(2)}(n) (1) was synthesized by evaporation methods using 3,3'-thiodipropionic acid (DPA) and cadmium nitrate as the starting materials. Compound 1 crystallizes in the monoclinic system, space group P2(1)/n with a = 7.5460(7), b = 13.372(3), c = 12.304(3) angstrom, beta = 95.95(3)degrees, V = 1234.8(4)angstrom(3), D-c = 1.940 g/cm(3), C6H16O8SCd, M-r = 360.65, F(000) = 720, mu(MoK alpha) = 1.960 mm(-1), Z = 4, R = 0.0460 and wR = 0.1185 for 1835 observed reflections (I > 2 sigma(I)), and R = 0.0591, wR = 0.1245 for all data. The complex has been characterized by elemental analysis, FT-IR, TG, PXRD and X-ray single-crystal structure analysis and the fluorescence property has also been studied. As a result, complex 1 possesses a two-dimensional (2-D) structure through DPA ligands interconnecting Cd2+ ions. Complex 1 emits the intense fluorescence of 420 nm in the solid state at room temperature.