文献类型：期刊文献

中文题名：A Novel 3D Zn-La Heterometallic Coordination Polymer Involving in situ Glycinate Ligand Synthesis

英文题名：A Novel 3D Zn-La Heterometallic Coordination Polymer Involving in situ Glycinate Ligand Synthesis

作者：SONG Wen-Donga[1];LI Shi-Jie[2];GUO Jian[2,4];TONG Shao-Wei[3];JI Li-Li[2];MIAO Dong-Liang[3];AN Jing-Bo[3];NG Seik Weng[5]

机构：[1]College of Science, Guangdong Ocean University, Zhanjiang 524088, China;[2]College of Environment Science and Engineering, Donghua University, Shanghai 200051, China;[3]College of Food Science and Technology,Guangdong Ocean University, Zhanjiang 524088, China;[4]Chinese and American Institute for Genetic Nutrition and HealthResearch, Guangdong Medical College, Zhanjiang 524023, China;[5]Department of Chemistry, University of Malaya, Kuala Lumpur 50603, Malaysia

年份：2012

卷号：31

期号：10

起止页码：1429

中文期刊名：结构化学

外文期刊名：Chinese Journal of Structural Chemistry

收录：Scopus、CSCD2011_2012、CSCD

基金：Supported by Public science and technology research fimds projects of ocean （No. 2000905021）, the Guangdong Oceanic Fisheries Technology Promotion Project （No. A2009003-018（c））, the Guangdong Chinese Academy of Sciences comprehensive strategic cooperation project （No. 2009B091300121 ）, and the Guangdong Province key project in the field of social development （No. A2009011-007（c））

语种：英文

中文关键词：异金属配位聚合物;原位合成;氨基乙酸;硝酸锌;香格里拉;配体;3D;镧系元素

外文关键词：hydrothermal synthesis, heterometallie complex, in situ glycinate synthesis

中文摘要：One novel 3D 3d-4f coordination polymer, [LaZn(glc)(ox)2(H2O)2]n (1, glc = glycinate, ox = oxalate), was obtained by the in situ synthesis of glycinate from the reaction of tetrazole-1-acetic acid, sodium oxalate, zinc nitrate and lanthanide oxide in the presence of a trace quantity of nitric acid under hydrothermal conditions. Compound 1 is of monoclinic, space group P21/n with a = 0.99601(9), b = 1.14592(10), c = 1.19107(10) nm and β = 108.7150(10)°. 1 exhibits an unusual 3D heterometallic coordination framework constructed by heterometallic dinuclear LaZn subunits and mixed ox and glc linkers with a uninodal 6-connected vme {33 .43 .58 .6} net.

外文摘要：One novel 3D 3d-4f coordination polymer, [LaZn（glc）（ox）2（H20）2]n （1, glc = glycinate, ox = oxalate）, was obtained by the in situ synthesis of glycinate from the reaction of tetrazole-l-acetic acid, sodium oxalate, zinc nitrate and lanthanide oxide in the presence of a trace quantity of nitric acid under hydrothermal conditions. Compound 1 is of monoclinic, space group P21/n with a = 0.99601（9）, b = 1.14592（10）, c = 1.19107（10） nm and β = 108.7150（10）°. 1 exhibits an unusual 3D heterometallic coordination framework constructed by heterometallic dinuclear LaZn subunits and mixed ox and glc linkers with a uninodal 6-connected vine {33.43.58.6} net.