文献类型：期刊文献

英文题名：A three-dimensional cadmium(II) coordination polymer: Poly[[[μ-4,4'- (propane-1,3-diyl)dipyridine-κ2 N:N](μ-3,3'- thiodipropionato-κ3 O,O':O)cadmium(II)] monohydrate]

作者：Hao, Xiao-Min[1,2]; Chen, Gang[1]; Gu, Chang-Sheng[2]; Liu, Ji-Wei[3]

机构：[1] Department of Chemistry, Harbin Institute of Technology, Harbin 150001, China; [2] Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang 524088, China; [3] College of Chemistry and Chemical Technology, Daqing Petroleum Institute, Daqing 163318, China

年份：2014

卷号：70

期号：7

起止页码：712

外文期刊名：Acta Crystallographica Section C: Structural Chemistry

收录：EI(收录号：20143318053275)、Scopus(收录号：2-s2.0-84905499181)

语种：英文

外文关键词：Ligands - Cadmium compounds - Carboxylation - Atoms - Crystal structure

外文摘要：In the title coordination polymer, {[Cd(C6H8O 4S)(C13H14N2)] H2O} n, the CdII atom displays a distorted octahedral coordination, formed by three carboxylate O atoms and one S atom from three different 3,3'-thiodipropionate ligands, and two N atoms from two different 4,4'-(propane-1,3-diyl)dipyridine ligands. The CdII centres are bridged through carboxylate O atoms of 3,3'-thiodipropionate ligands and through N atoms of 4,4'-(propane-1,3-diyl)dipyridine ligands to form two different one-dimensional chains, which intersect to form a two-dimensional layer. These two-dimensional layers are linked by S atoms of 3,3'-thiodipropionate ligands from adjacent layers to form a three-dimensional network. ? 2014 International Union of Crystallography.