文献类型：期刊文献

英文题名：μ-aqua-bis(μ-4-chlorobenzoato)bis[(4-chlorobenzoato)(1,10-phenanthroline)manganese(II)]

作者：Shen, Yu-Li; Sun, Sheng-Li; Song, Wen-Dong

机构：[1]Guang Dong Ocean Univ, Coll Sci, Zhan Jiang 524088, Peoples R China;[2]Guang Dong Ocean Univ, Coll Informat, Zhan Jiang 524088, Peoples R China;[3]Guang Dong Ocean Univ, Monitoring Ctr Marine Resurces & Environm, Zhan Jiang 524088, Peoples R China

年份：2007

卷号：63

期号：5

起止页码：M1309

外文期刊名：ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

收录：SCI-EXPANDED(收录号：WOS:000248080100063)、、Scopus(收录号：2-s2.0-57349086994)、WOS

语种：英文

外文关键词：single-crystal X-ray study; T=293 K; mean sigma(C-C)=0.006 angstrom; R factor=0.045; wR factor=0.122; data-to-parameter ratio=14.9

外文摘要：The title complex molecule, [Mn-2(C7H4ClO2)(4)(C12H8N2)(2)-( H2O)], possesses crystallographically imposed C-2 symmetry. Each Mn-II atom is coordinated by three carboxyl O atoms from three 4-chlorobenzoate ligands, two N atoms from one 1,10-phenanthroline ligand and one bridging water molecule in a distorted octahedral coordination geometry. The Mn . . . Mn separation is 3.512 (3) angstrom. Symmetrically related dinuclear molecules form chains parallel to the c axis via pi-pi stacking interactions.