详细信息
文献类型:期刊文献
英文题名:Diaquabis[2-(benzyloxy)acetato]-cobalt(II)
作者:Chen, Chun-Liang[2];Sun, Sheng-Li[2];Gu, Chang-Sheng[1];Song, Weng-Dong[1];Hao, Xiao-Min[1]
机构:[1]Guangdong Ocean Univ, Dept Appl Chem, Zhanjiang 524088, Peoples R China;[2]Guangdong Ocean Univ, Monitoring Ctr Marine Resources & Environm, Zhanjiang 524088, Peoples R China
年份:2008
卷号:64
起止页码:M890
外文期刊名:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
收录:SCI-EXPANDED(收录号:WOS:000257167600030)、、Scopus(收录号:2-s2.0-46749134320)、WOS
语种:英文
外文摘要:In the mononuclear title complex, [Co(C9H9O3)(2)(H2O)(2)], each Co-II atom is located on an inversion center and is hexacoordinated by four O atoms from two benzyloxyacetate ligands [Co-O bond lengths = 2.0487 (9) and 2.1090 (9) angstrom] and two water molecules [Co-O bond length = 2.0873 (9) angstrom] in a distorted octahedral geometry. In the crystal structure, intermolecular hydrogen bonds and pi-pi stacking interactions [centroid-centroid distance between phenyl rings = 3.692 (2) angstrom] link the molecules into a supramolecular structure.
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