文献类型：期刊文献

中文题名：Syntheses and Crystal Structures of Cd(Ⅱ) and Ni(Ⅱ) Complexes Containing Flexible Sulfide and Nitrogen Heterocyclic Ligands

英文题名：Syntheses and Crystal Structures of Cd(Ⅱ) and Ni(Ⅱ) Complexes Containing Flexible Sulfide and Nitrogen Heterocyclic Ligands

作者：郝晓敏[1];谷长生[1];韩丝银[2];苗艳丽[1];李泳[1];宋文东[3]

机构：[1]Department of Applied Chemistry, Guangdong Ocean University;[2]College of Food Science and Technology,Guangdong Ocean University;[3]School of Petrochemical & Energy Engineering,Zhejiang Ocean University

年份：2015

卷号：34

期号：3

起止页码：408

中文期刊名：Chinese Journal of Structural Chemistry

外文期刊名：结构化学（英文）

收录：CSCD2015_2016、Scopus、CSCD

基金：the Foundation of Guangdong Province(No.S2012020011054 and 2011B090400415);Zhanjiang Municipality(No.2011C3108001)

语种：中文

中文关键词：2,2＇-dithiosalicylicacid, in situ reaction, crystal structure;

外文关键词：2,2＇-dithiosalicylicacid, in situ reaction, crystal structure;

中文摘要：Two new coordination polymers [Cd（EBLA）（ip）（H2O）] （1） and [Ni（EBSA） （im）2（H2O）], （2） were synthesized by hydrothermal and solution methods using 2,2＇-dithio- salicylicacid （EBSA）, lH-imidazo[4,5-f][1,10]phenanthroline （ip）, imidazole （im）, Cd（NO3）2-4H2O and Ni（NOa）z＇6H20. The complexes were characterized by elemental analysis and FT-IR. Meanwhile, the crystal structures, fluorescence properties of complex 1 and thermogravimetrie analysis of complex 2 have been studied. In complex 1, 2,2＇-dicarboxydiphenylthioether （EBLA） was prepared with 2,2＇-dithiosalicylicacid （EBSA） in situ reaction by hydrothermal method. Complex 1 is a dinuclear structure and Cd2＋ is five-coordinated in a distorted trigonal bipyramidal geometry. Complex 2 is a one-dimensional infinite linear chain and Ni2＋ is six-coordinated to form a distorted octahedral geometry. Hydrogen bonding and π-π interactions are observed in these complexes.

外文摘要：Two new coordination polymers [Cd（EBLA）（ip）（H2O）] （1） and [Ni（EBSA） （im）2（H2O）], （2） were synthesized by hydrothermal and solution methods using 2,2＇-dithio- salicylicacid （EBSA）, lH-imidazo[4,5-f][1,10]phenanthroline （ip）, imidazole （im）, Cd（NO3）2-4H2O and Ni（NOa）z＇6H20. The complexes were characterized by elemental analysis and FT-IR. Meanwhile, the crystal structures, fluorescence properties of complex 1 and thermogravimetrie analysis of complex 2 have been studied. In complex 1, 2,2＇-dicarboxydiphenylthioether （EBLA） was prepared with 2,2＇-dithiosalicylicacid （EBSA） in situ reaction by hydrothermal method. Complex 1 is a dinuclear structure and Cd2＋ is five-coordinated in a distorted trigonal bipyramidal geometry. Complex 2 is a one-dimensional infinite linear chain and Ni2＋ is six-coordinated to form a distorted octahedral geometry. Hydrogen bonding and π-π interactions are observed in these complexes.