文献类型：期刊文献

英文题名：Transition-Metal-Free Borylation of Alkynes and Alkenes

作者：Deng, Chun M.[1];Ma, Yi F.[1];Wen, Yan M.[1]

机构：[1]Guangdong Ocean Univ, Fac Chem & Environm Sci, Zhanjiang 524088, Peoples R China

年份：2018

卷号：3

期号：4

起止页码：1202

外文期刊名：CHEMISTRYSELECT

收录：SCI-EXPANDED(收录号：WOS:000423764200031)、、Scopus(收录号：2-s2.0-85045845057)、WOS

基金：Authors of this paper appreciate financial support from Guangdong Natural Science Foundation (No. 2016 A030313750), Project of Enhancing School with Innovation of Guangdong Ocean University (No. GDOU2017052502), Zhanjiang Natural Science Foundation (No. A15445, No. A14457).

语种：英文

外文关键词：Alkenes; Alkynes; Base; Borylation; Metal-free

外文摘要：The transition metal-free method for borylation of alkynes and alkenes with bis(pinacolato)diboron has been developed, producing the correspondent organoborons under mild reaction conditions. This reaction was an efficient, practical and environment-friendly process which brings forth vinylboronate products with excellent regioselectivity in the borylation of alkynes with bis(pinacolato)diboron, while in the meantime the diboryl alkanes were obtained using alkenes as substrates.