文献类型：期刊文献

英文题名：Aquabis(1H-imidazole-kappa N-3)bis(4-methylbenzoato-kappa O-2,O ')cadmium(II)

作者：Song, Wen-Dong[1];Ji, Li-Li[1];Huang, Xiang-Hu[2]

机构：[1]Guangdong Ocean Univ, Coll Sci, Zhanjiang 524088, Peoples R China;[2]Guangdong Ocean Univ, Coll Fisheries, Zhanjiang 524088, Peoples R China

年份：2008

卷号：64

起止页码：M714

外文期刊名：ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

收录：SCI-EXPANDED(收录号：WOS:000255450100082)、、WOS

语种：英文

外文摘要：In the title compound, [Cd(C8H7O2)(2)(C3H4N2)(2)(H2O)], the Cd-II atom is coordinated by four carboxylate O atoms from two bidentate chelating 4-methylbenzoate ligands, two N atoms from two imidazole ligands and one water molecule in a distorted pentagonal bipyramidal geometry. Intermolecular O-H center dot center dot center dot O hydrogen bonds between the coordinated water molecule and the carboxylate O atoms of 4-methylbenzoate lead to an infinite chain. These chains are further self-assembled into a two-dimensional layer through O-H center dot center dot center dot O hydrogen bonds between the imidazole ligands and carboxylate groups. One of the imidazole ligands is disordered over two positions with site-occupancy factors of 0.737 (4) and 0.263 (4).