文献类型：会议论文

英文题名：Synthesis, Structure, Luminescest and Thermal Stable Properties of a Silver(I) Coordination Polymer Constructed from 2,4-Dichlorophenoxyacetic Acid and 1,3-Bis(4-pyridyl) Propane Ligands

作者：Hao, Xiao Min[1,2]; Chen, Gang[1]; Gu, Chang Sheng[2]

机构：[1] Department of Chemistry, Harbin Institute of Technology, Harbin 150001, China; [2] Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang 524088, China

会议论文集：Biological Systems and Materials

会议日期：April 1, 2014 - April 2, 2014

会议地点：Seoul, Korea, Republic of

语种：英文

外文关键词：Chelation - Single crystals - Coordination reactions - Silver compounds - Thermogravimetric analysis

外文摘要：A novel complex of [Ag(poa)(bpp)]n(poa:2,4-Dichlorophenoxyacetic acid;bpp: 1,3-Bis (4-pyridyl) propane) was synthesized and characterized by elemental analysis, IR, X-ray single crystal diffraction. The title complex belongs to Monoclinic system with space group P21/c, a=8.849(4)A, b=26.654(13)A, c=9.821(5)A, α =90°, β =111.257(8)°, γ =90°,V=2158.7(17)A3, Z=4,Dc=1.619 g/cm3, μ=1.206 mm-1, F(000)=1056. Final indices is R=0.0331, wR=0.0851. Therm al stability and luminescent property of compound have also been nvestigated. ? (2014) Trans Tech Publications, Switzerland.