文献类型：会议论文

英文题名：Synthesis, characterization, structure and thermal decomposition of a Ag(I) complex derived from 3-pyridinesulfonate and 1,4-bis(2-methyl-imidazol-1-yl)butane

作者：Hao, Xiao Min[1,2]; Chen, Gang[1]; Gu, Chang Sheng[2]

机构：[1] Department of Chemistry, Harbin Institute of Technology, Harbin 150001, China; [2] Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang 524088, China

会议论文集：Biological Systems and Materials

会议日期：April 1, 2014 - April 2, 2014

会议地点：Seoul, Korea, Republic of

语种：英文

外文关键词：Silver compounds - Butane - Single crystals - Thermogravimetric analysis - Decomposition

外文摘要：A novel complex of [Ag(bib)(3-pySO3)]n (3-pySO3:3-pyridinesulfonate; bib 1, 4-bis (2-methyl-imidazol-1-yl) butane) was synthesized and characterized by elemental analysis, IR, X-ray single crystal diffraction. The title complex belongs to triclinic system with space group P-1, a=7.8030(16)A, b=8.0070(16)A, c=10.742(2)A,α=84.64(3)°,β=82.33(3)°,γ=82.76(3)°, V=657.8(2)A3, Z=2, Dc=1.894g/cm3, μ= 1.697mm-1, F(000)= 374. Final indices is R =0.0480, wR =0.1169. Thermal stability and luminescent property of compound have also been investigated. ? (2014) Trans Tech Publications, Switzerland.