详细信息
文献类型:期刊文献
英文题名:Diaquabis(2,4-dichlorophenoxyacetato-κO)-bis(1H-imidazole-κN3)cobalt(II)
作者:Hao, Xiao-Min; Gu, Chang-Sheng; Song, Wen-Dong; Ma, De-Yun; Liu, Zhong-Yuan
机构:[1]Guangdong Univ Ocean, Dept Appl Chem, Zhanjiang 524006, Peoples R China
年份:2006
卷号:62
起止页码:M2618
外文期刊名:ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
收录:SCI-EXPANDED(收录号:WOS:000240914400088)、、WOS
语种:英文
外文摘要:The Co-II atom in the mononuclear title complex, [ Co( C8H5Cl2O3)(2)( C3H4N2)(2)( H2O)(2)], lies on an inversion center. The Co-II atom has an octahedral coordination, involving two carboxylate O atoms of two monodentate 2,4-dichlorophenoxyacetate ligands, two N atoms of imidazole ligands and two water molecules. Intermolecular O-(HO)-O-... hydrogen bonds give rise to chains, which are linked by N-(HO)-O-.... hydrogen bonds, forming a sheet structure. The molecules are further linked by pi-pi stacking interactions, generating a two-dimensional supramolecular network.
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