文献类型：期刊文献

中文题名：GC-MS法同时测定水产品中6种丁香酚类麻醉剂的残留量

英文题名：Determination of 6 Clove Phenol Drug Residues in Aquatic Products by Gas Chromatography-mass Spectrometry(GC-MS) Method

作者：陈焕[1];黄和[1];高平[2];曹湛慧[1];孙力军[1];吉宏武[1]

机构：[1]广东省水产品加工与安全重点实验室广东普通高等学校水产品深加工重点实验室广东海洋大学食品科技学院;[2]湛江市食品药品检验所

年份：2017

卷号：0

期号：7

起止页码：305

中文期刊名：食品工业

外文期刊名：The Food Industry

收录：北大核心2014、北大核心

基金：广东省科技计划项目(2014A020208121);广东海洋大学创新强校项目(GDOU2013050205;GDOU2014050203)

语种：中文

中文关键词：气相色谱-质谱;丁香酚类;水产品;残留量

外文关键词：gas chromatography-mass spectrometry （GC-MS）; clove phenol; aquatic products; residual quantity

中文摘要：建立了同时检测水产品中6种丁香酚类麻醉剂残留量的气相色谱-质谱(GC-MS)检测方法。样品经乙腈超声提取,分散固相萃取净化后氮吹浓缩、定容,用气相色谱-质谱仪进行测定,外标法定量。6种丁香酚类化合物在1.0~200.0 μg/L的浓度范围内线性关系良好,相关系数R^2为0.9956~0.9995。又分别在罗非鱼、南美白对虾以及扇贝肌肉样品中添加1.0~10.0 μg/kg的混合标准溶液,测定平均回收率在82.2%~100.7%范围内,相对标准偏差在0.6%~7.4%之间。方法的定量限(LOQ),丁香酚、甲基丁香酚、异丁香酚、乙酰基异丁香酚为1.0 μg/kg,甲基异丁香酚和乙酸丁香酚酯为0.5 μg/kg。

外文摘要：A gas chromatography-mass spectrometry （GC-MS） method had been developed for the detection of six kinds of eugenol drug residues in aquatic products at the same time. Sample was ultrasonic extracted by acetonitrile, using dispersive solid-phase extraction （DSPE） purification and then drying by nitrogen, volume constanted with acetone, determined by gas chromatograph-mass spectrometry. External standard calibration was adopted in the determination. Six kinds of eugenol type of anesthetic showed good linearity in the concentrations range of 1.0-200.0 μg/L for the standard solutions carves, and all of the correlation coefficients （R2） were in 0.995 6-0.999 5. At the spiked levels of 1.0-10.0μg/kg in tilapia, south America white shrimp and scallop muscle, the average recoveries were 82.2%-100.7%. The relative standard deviations were 0.6%-7.4%. The limit of quantity （LOQ） of eugenol, methyl eugenol, iso-eugenol and acetyl iso-eugenol was 1.0 μg/kg, and that of methyl iso-eugenol, eugenol acetate was 0.5 μg/kg.