文献类型：期刊文献

英文题名：Syntheses, Crystal Structures of Zn(II) and Mn(II) Complexes with Flexible Sulfur Containing Aromatic Acid and Nitrogen Heterocyclic Ligands

作者：Hao Xiao-Min[1];Gu Chang-Sheng[1];Han Si-Yin[2];Fan Run-Zhen[1];Li Yong[1];Song Wen-Dong[3]

机构：[1]Guangdong Ocean Univ, Dept Appl Chem, Zhanjiang 524088, Guangdong, Peoples R China;[2]Guangdong Ocean Univ, Coll Food Sci & Technol, Zhanjiang 524088, Guangdong, Peoples R China;[3]Zhejiang Ocean Univ, Sch Petrochem & Energy Engn, Zhoushan 316000, Zhejiang, Peoples R China

年份：2015

卷号：31

期号：2

起止页码：369

外文期刊名：CHINESE JOURNAL OF INORGANIC CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:000351319200022)、、Scopus(收录号：2-s2.0-84942793103)、WOS

基金：The authors thank the foundation of Guangdong province and Zhanjiang city (grant No. S2012020011054, 2011B090400415 and 2011C3108001) and chemical experiment center of Guangdong Ocean University for supporting this work.

语种：英文

外文关键词：2,2 '-dithiosalicylic acid; 2,2 '-dicarboxydiphenylthioether; in situ reaction; crystal structure

外文摘要：Two coordination polymers [Zn(EBLA)(2,2'-bipy)(H2O)1 (1) and [Mn (EBSA)(im)(2)(H2O)(n), (2) were synthesized by hydrothermal and evaporation methods using 2,2'-dithiosalicylic acid (EBSA), 2,2'-dipyridyl, imidazole, Zn(NO3)(2)center dot 6H(2)O and Mn(NO3)(2)center dot 4H(2)O. And the complexes were characterized by elemental analysis, FTIR and thermogrktvimetrie analysis (TGA), meanwhile the crystal structures and fluorescence properties of the complex 1 have been studied. In complex 1, 2,2'-dicarboxydiphenylthioether (EBLA) was prepared with 2,2'-dithiosalicylic acid (EBSA) in situ. reaction by hydrothermal method. The complex 1 is a dinuclear structure and Zn2+ ion is five-coordination in a distorted square pyramidal geometry; The complex 2 is a one-dimensional infinite linear chain and Mn2+ ion is six-coordination in a distorted octahedral geometry. Hydrogen bonding and IT 7T interactions are observed in these complexes. CCDC: 998513, 1; 1000616, 2.