文献类型：期刊文献

中文题名：3-氯-2-氯甲基-1-丙烯引发苯乙烯原子转移自由基聚合的研究

英文题名：ATRP OF STYRENE INITIATED BY 3-CHLORO-2-(CHLOROMETHYL)-1-PROPENE

作者：刘群峰[1];李思东[1];何卫东[2]

机构：[1]广东海洋大学理学院应用化学系;[2]中国科学技术大学高分子科学与工程系

年份：2007

期号：6

起止页码：582

中文期刊名：高分子学报

外文期刊名：Acta Polymerica Sinica

收录：SCI-EXPANDED(收录号：WOS:000247450800016)、CSTPCD、、北大核心2004、Scopus、CSCD2011_2012、WOS、北大核心、CSCD

基金：国家自然科学基金(基金号20104006)资助项目

语种：中文

中文关键词：活性聚合;双官能性引发剂;烯丙基

外文关键词：Living polymerization, Difunctional initiator, Allyl group

中文摘要：3-Chloro-2-（chloromethyl）-1-propene（CCMP） was synthesized and used to initiate atom transfer radical polymerization（ATRP） of styrene catalyzed by copper（Ⅰ） chloride/2,2′-bipyridine at 125℃.As a difunctional initiator,CCMP can initiate ATRP of styrene with two living end sites at the same time.The structure of the obtained α,ω-chloropolystyrene was confirmed by（）1H-NMR spectra.The living character of the ATRP process is indicated by narrow molecular weight distributions of the obtained polystyrene（Mw/Mn<1.5）,a linear（ln（[M]0/[M]）） versus time profile and predictable molecular weights proportional to monomer conversion.

外文摘要：3-Chloro-2-（chloromethyl）-1-propene （CCMP） was synthesized and used to initiate atom transfer radical polymerization （ATRP） of styrene catalyzed by copper （ Ⅰ ） chloride/2,2′-bipyridine at 125℃. As a difunctional initiator, CCMP can initiate ATRP of styrene with two living end sites at the same time. The structure of the obtained α,ω-chloropolystyrene was confirmed by ^1H-NMR spectra. The living character of the ATRP process is indicated by narrow molecular weight distributions of the obtained polystyrene （Mw/Mn 〈 1.5）, a linear In（ [ M]0/[ M] ） versus time profile and predictable molecular weights proportional to monomer conversion.